Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling.
We report the rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF-8, by ball-milling. The resultant amorphous ZIF-8 (a(m)ZIF-8) possesses a continuous random network (CRN) topology with a higher density and a lower porosity than its crystalline counterpart. A decr...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2012
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| _version_ | 1797097973090353152 |
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| author | Cao, S Bennett, T Keen, D Goodwin, A Cheetham, A |
| author_facet | Cao, S Bennett, T Keen, D Goodwin, A Cheetham, A |
| author_sort | Cao, S |
| collection | OXFORD |
| description | We report the rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF-8, by ball-milling. The resultant amorphous ZIF-8 (a(m)ZIF-8) possesses a continuous random network (CRN) topology with a higher density and a lower porosity than its crystalline counterpart. A decrease in thermal stability upon amorphization is also evident. |
| first_indexed | 2024-03-07T05:02:59Z |
| format | Journal article |
| id | oxford-uuid:d8f42b87-18b2-45fc-a91c-2ab29b6b1836 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:02:59Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:d8f42b87-18b2-45fc-a91c-2ab29b6b18362022-03-27T08:52:27ZAmorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d8f42b87-18b2-45fc-a91c-2ab29b6b1836EnglishSymplectic Elements at Oxford2012Cao, SBennett, TKeen, DGoodwin, ACheetham, AWe report the rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF-8, by ball-milling. The resultant amorphous ZIF-8 (a(m)ZIF-8) possesses a continuous random network (CRN) topology with a higher density and a lower porosity than its crystalline counterpart. A decrease in thermal stability upon amorphization is also evident. |
| spellingShingle | Cao, S Bennett, T Keen, D Goodwin, A Cheetham, A Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling. |
| title | Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling. |
| title_full | Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling. |
| title_fullStr | Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling. |
| title_full_unstemmed | Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling. |
| title_short | Amorphization of the prototypical zeolitic imidazolate framework ZIF-8 by ball-milling. |
| title_sort | amorphization of the prototypical zeolitic imidazolate framework zif 8 by ball milling |
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