Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
<p>This thesis describes the synthesis and anion recognition properties of a series of halogen and hydrogen bonding acyclic and interlocked host receptors and the use of the inclusion supramolecular chemistry of cucurbit[n]uril derivatives in switchable luminescent output.</p> <p>&...
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| Format: | Thèse |
| Langue: | English |
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2016
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| _version_ | 1826299562758766592 |
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| author | Hess, A |
| author2 | Beer, P |
| author_facet | Beer, P Hess, A |
| author_sort | Hess, A |
| collection | OXFORD |
| description | <p>This thesis describes the synthesis and anion recognition properties of a series of halogen and hydrogen bonding acyclic and interlocked host receptors and the use of the inclusion supramolecular chemistry of cucurbit[n]uril derivatives in switchable luminescent output.</p> <p><b>Chapter 1</b> introduces the field of anion supramolecular chemistry and the properties of cucurbit[n]uril macrocycles which pertain to the research detailed in subsequent chapters.</p> <p><b>Chapter 2</b> describes the synthesis and anion recognition properties of a new class of chelating, halogen and hydrogen bonding host molecules. The halogen bonding enhanced selectivity for the Br- anion is demonstrated.</p> <p><b>Chapter 3</b> probes the anion recognition characteristics of a series of novel halogen and hydrogen bonding motifs. Evidence for intramolecular hydrogen bond enhanced halogen bonding recognition of halides is presented and the selective recognition of the anion H2PO4- by a [3]rotaxane host is displayed.</p> <p><b>Chapter 4</b> discusses the redox-mediated modulation of the luminescent output of a series of visible and near-infrared emitting lanthanide complexes within cucurbit[8]uril based ternary complexes.</p> <p><b>Chapter 5</b> describes the experimental procedures and characterisation of the compounds presented in Chapters 2-4.</p> <p><b>Chapter 6</b> summarises the conclusions of this thesis.</p> |
| first_indexed | 2024-03-07T05:03:49Z |
| format | Thesis |
| id | oxford-uuid:d93bf9e5-41b7-499b-8e69-4cd6b2978294 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:03:49Z |
| publishDate | 2016 |
| record_format | dspace |
| spelling | oxford-uuid:d93bf9e5-41b7-499b-8e69-4cd6b29782942022-03-27T08:54:21ZHalogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent outputThesishttp://purl.org/coar/resource_type/c_db06uuid:d93bf9e5-41b7-499b-8e69-4cd6b2978294AnionsSupramolecular chemistryEnglishORA Deposit2016Hess, ABeer, P<p>This thesis describes the synthesis and anion recognition properties of a series of halogen and hydrogen bonding acyclic and interlocked host receptors and the use of the inclusion supramolecular chemistry of cucurbit[n]uril derivatives in switchable luminescent output.</p> <p><b>Chapter 1</b> introduces the field of anion supramolecular chemistry and the properties of cucurbit[n]uril macrocycles which pertain to the research detailed in subsequent chapters.</p> <p><b>Chapter 2</b> describes the synthesis and anion recognition properties of a new class of chelating, halogen and hydrogen bonding host molecules. The halogen bonding enhanced selectivity for the Br- anion is demonstrated.</p> <p><b>Chapter 3</b> probes the anion recognition characteristics of a series of novel halogen and hydrogen bonding motifs. Evidence for intramolecular hydrogen bond enhanced halogen bonding recognition of halides is presented and the selective recognition of the anion H2PO4- by a [3]rotaxane host is displayed.</p> <p><b>Chapter 4</b> discusses the redox-mediated modulation of the luminescent output of a series of visible and near-infrared emitting lanthanide complexes within cucurbit[8]uril based ternary complexes.</p> <p><b>Chapter 5</b> describes the experimental procedures and characterisation of the compounds presented in Chapters 2-4.</p> <p><b>Chapter 6</b> summarises the conclusions of this thesis.</p> |
| spellingShingle | Anions Supramolecular chemistry Hess, A Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| title | Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| title_full | Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| title_fullStr | Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| title_full_unstemmed | Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| title_short | Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| title_sort | halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output |
| topic | Anions Supramolecular chemistry |
| work_keys_str_mv | AT hessa halogenandhydrogenbondinghoststructuresforanionrecognitionandternarycomplexesformodulatingluminescentoutput |