Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output

<p>This thesis describes the synthesis and anion recognition properties of a series of halogen and hydrogen bonding acyclic and interlocked host receptors and the use of the inclusion supramolecular chemistry of cucurbit[n]uril derivatives in switchable luminescent output.</p> <p>&...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखक: Hess, A
अन्य लेखक: Beer, P
स्वरूप: थीसिस
भाषा:English
प्रकाशित: 2016
विषय:
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author Hess, A
author2 Beer, P
author_facet Beer, P
Hess, A
author_sort Hess, A
collection OXFORD
description <p>This thesis describes the synthesis and anion recognition properties of a series of halogen and hydrogen bonding acyclic and interlocked host receptors and the use of the inclusion supramolecular chemistry of cucurbit[n]uril derivatives in switchable luminescent output.</p> <p><b>Chapter 1</b> introduces the field of anion supramolecular chemistry and the properties of cucurbit[n]uril macrocycles which pertain to the research detailed in subsequent chapters.</p> <p><b>Chapter 2</b> describes the synthesis and anion recognition properties of a new class of chelating, halogen and hydrogen bonding host molecules. The halogen bonding enhanced selectivity for the Br- anion is demonstrated.</p> <p><b>Chapter 3</b> probes the anion recognition characteristics of a series of novel halogen and hydrogen bonding motifs. Evidence for intramolecular hydrogen bond enhanced halogen bonding recognition of halides is presented and the selective recognition of the anion H2PO4- by a [3]rotaxane host is displayed.</p> <p><b>Chapter 4</b> discusses the redox-mediated modulation of the luminescent output of a series of visible and near-infrared emitting lanthanide complexes within cucurbit[8]uril based ternary complexes.</p> <p><b>Chapter 5</b> describes the experimental procedures and characterisation of the compounds presented in Chapters 2-4.</p> <p><b>Chapter 6</b> summarises the conclusions of this thesis.</p>
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spelling oxford-uuid:d93bf9e5-41b7-499b-8e69-4cd6b29782942022-03-27T08:54:21ZHalogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent outputThesishttp://purl.org/coar/resource_type/c_db06uuid:d93bf9e5-41b7-499b-8e69-4cd6b2978294AnionsSupramolecular chemistryEnglishORA Deposit2016Hess, ABeer, P<p>This thesis describes the synthesis and anion recognition properties of a series of halogen and hydrogen bonding acyclic and interlocked host receptors and the use of the inclusion supramolecular chemistry of cucurbit[n]uril derivatives in switchable luminescent output.</p> <p><b>Chapter 1</b> introduces the field of anion supramolecular chemistry and the properties of cucurbit[n]uril macrocycles which pertain to the research detailed in subsequent chapters.</p> <p><b>Chapter 2</b> describes the synthesis and anion recognition properties of a new class of chelating, halogen and hydrogen bonding host molecules. The halogen bonding enhanced selectivity for the Br- anion is demonstrated.</p> <p><b>Chapter 3</b> probes the anion recognition characteristics of a series of novel halogen and hydrogen bonding motifs. Evidence for intramolecular hydrogen bond enhanced halogen bonding recognition of halides is presented and the selective recognition of the anion H2PO4- by a [3]rotaxane host is displayed.</p> <p><b>Chapter 4</b> discusses the redox-mediated modulation of the luminescent output of a series of visible and near-infrared emitting lanthanide complexes within cucurbit[8]uril based ternary complexes.</p> <p><b>Chapter 5</b> describes the experimental procedures and characterisation of the compounds presented in Chapters 2-4.</p> <p><b>Chapter 6</b> summarises the conclusions of this thesis.</p>
spellingShingle Anions
Supramolecular chemistry
Hess, A
Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
title Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
title_full Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
title_fullStr Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
title_full_unstemmed Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
title_short Halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
title_sort halogen and hydrogen bonding host structures for anion recognition and ternary complexes for modulating luminescent output
topic Anions
Supramolecular chemistry
work_keys_str_mv AT hessa halogenandhydrogenbondinghoststructuresforanionrecognitionandternarycomplexesformodulatingluminescentoutput