Near-threshold H/D exchange in CD₃CHO photodissociation.

Measuring the isotopic abundance of hydrogen versus deuterium atoms is a key method for interrogating reaction pathways in chemistry. H/D 'scrambling' is the intramolecular rearrangement of labile isotopes of hydrogen atoms and when it occurs through unanticipated pathways can complicate t...

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Autori principali: Heazlewood, B, Maccarone, A, Andrews, D, Osborn, D, Harding, L, Klippenstein, S, Jordan, M, Kable, S
Natura: Journal article
Lingua:English
Pubblicazione: 2011