Near-threshold H/D exchange in CD₃CHO photodissociation.

Measuring the isotopic abundance of hydrogen versus deuterium atoms is a key method for interrogating reaction pathways in chemistry. H/D 'scrambling' is the intramolecular rearrangement of labile isotopes of hydrogen atoms and when it occurs through unanticipated pathways can complicate t...

Полное описание

Библиографические подробности
Главные авторы: Heazlewood, B, Maccarone, A, Andrews, D, Osborn, D, Harding, L, Klippenstein, S, Jordan, M, Kable, S
Формат: Journal article
Язык:English
Опубликовано: 2011