A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE)
The readily available complex [Ti(NBut)Cl2(Bu tpy)2] (Butpy = 4-tert-butylpyridine) is a useful precursor to a range of sandwich- and half-sandwich titanium imido derivatives including [Ti(η-C9H4Me3) (NBut)Cl(Butpy)] (C9H4Me3 = trimethylindenyl), [Ti(η-C5H5)2(NBu t)(Butpy)], [Ti(dmbpz)(NBut)Cl(Bu tp...
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| Format: | Journal article |
| Language: | English |
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1994
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| _version_ | 1797098188090376192 |
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| author | Dunn, S Batsanov, A Mountford, P |
| author_facet | Dunn, S Batsanov, A Mountford, P |
| author_sort | Dunn, S |
| collection | OXFORD |
| description | The readily available complex [Ti(NBut)Cl2(Bu tpy)2] (Butpy = 4-tert-butylpyridine) is a useful precursor to a range of sandwich- and half-sandwich titanium imido derivatives including [Ti(η-C9H4Me3) (NBut)Cl(Butpy)] (C9H4Me3 = trimethylindenyl), [Ti(η-C5H5)2(NBu t)(Butpy)], [Ti(dmbpz)(NBut)Cl(Bu tpy)] [dmbpz = tris(3,5-dimethylpyrazolyl) borate] and [Ti(η4-Mentaa)(NBut)] {n = 4 or 8; Me (4 or 8)taa = (tetra- or octa-)methyl-dibenzotetraaza[14]annulene respectively}. |
| first_indexed | 2024-03-07T05:06:02Z |
| format | Journal article |
| id | oxford-uuid:d9f2e91b-9d25-4b34-ab00-b2827347f4d3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:06:02Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:d9f2e91b-9d25-4b34-ab00-b2827347f4d32022-03-27T08:59:39ZA GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d9f2e91b-9d25-4b34-ab00-b2827347f4d3EnglishSymplectic Elements at Oxford1994Dunn, SBatsanov, AMountford, PThe readily available complex [Ti(NBut)Cl2(Bu tpy)2] (Butpy = 4-tert-butylpyridine) is a useful precursor to a range of sandwich- and half-sandwich titanium imido derivatives including [Ti(η-C9H4Me3) (NBut)Cl(Butpy)] (C9H4Me3 = trimethylindenyl), [Ti(η-C5H5)2(NBu t)(Butpy)], [Ti(dmbpz)(NBut)Cl(Bu tpy)] [dmbpz = tris(3,5-dimethylpyrazolyl) borate] and [Ti(η4-Mentaa)(NBut)] {n = 4 or 8; Me (4 or 8)taa = (tetra- or octa-)methyl-dibenzotetraaza[14]annulene respectively}. |
| spellingShingle | Dunn, S Batsanov, A Mountford, P A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE) |
| title | A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE) |
| title_full | A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE) |
| title_fullStr | A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE) |
| title_full_unstemmed | A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE) |
| title_short | A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE) |
| title_sort | general route to sandwich and half sandwich titanium imido complexes x ray structure of ti eta 4 me 8 taa nbu t me 4 taa tetramethyldibenzotetraaza 14 annulene |
| work_keys_str_mv | AT dunns ageneralroutetosandwichandhalfsandwichtitaniumimidocomplexesxraystructureoftieta4me8taanbutme4taatetramethyldibenzotetraaza14annulene AT batsanova ageneralroutetosandwichandhalfsandwichtitaniumimidocomplexesxraystructureoftieta4me8taanbutme4taatetramethyldibenzotetraaza14annulene AT mountfordp ageneralroutetosandwichandhalfsandwichtitaniumimidocomplexesxraystructureoftieta4me8taanbutme4taatetramethyldibenzotetraaza14annulene AT dunns generalroutetosandwichandhalfsandwichtitaniumimidocomplexesxraystructureoftieta4me8taanbutme4taatetramethyldibenzotetraaza14annulene AT batsanova generalroutetosandwichandhalfsandwichtitaniumimidocomplexesxraystructureoftieta4me8taanbutme4taatetramethyldibenzotetraaza14annulene AT mountfordp generalroutetosandwichandhalfsandwichtitaniumimidocomplexesxraystructureoftieta4me8taanbutme4taatetramethyldibenzotetraaza14annulene |