Synthesis and Structure of the New Ternary Nitride SrTiN(2).
A new ternary nitride, SrTiN(2), has been synthesized by the solid-state reaction of Sr(2)N with TiN and characterized by powder X-ray diffraction. SrTiN(2) crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Å, c = 7.6985(4) Å, Z = 2) and is isostructural with KCoO(2). Titanium is coor...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1998
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| _version_ | 1826299754758275072 |
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| author | Gregory, D Barker, MG Edwards, P Siddons, D |
| author_facet | Gregory, D Barker, MG Edwards, P Siddons, D |
| author_sort | Gregory, D |
| collection | OXFORD |
| description | A new ternary nitride, SrTiN(2), has been synthesized by the solid-state reaction of Sr(2)N with TiN and characterized by powder X-ray diffraction. SrTiN(2) crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Å, c = 7.6985(4) Å, Z = 2) and is isostructural with KCoO(2). Titanium is coordinated to five nitrogens in a distorted square-based pyramidal geometry, forming layers of edge-sharing pyramids which stack along the (001) direction. Strontium is situated between the Ti-N layers and is coordinated to five nitrogen atoms. The title compound is only the third example of a ternary titanium nitride. |
| first_indexed | 2024-03-07T05:06:45Z |
| format | Journal article |
| id | oxford-uuid:da301352-256f-4455-acfc-d7ab0f6b7009 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:06:45Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:da301352-256f-4455-acfc-d7ab0f6b70092022-03-27T09:01:20ZSynthesis and Structure of the New Ternary Nitride SrTiN(2).Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:da301352-256f-4455-acfc-d7ab0f6b7009EnglishSymplectic Elements at Oxford1998Gregory, DBarker, MGEdwards, PSiddons, DA new ternary nitride, SrTiN(2), has been synthesized by the solid-state reaction of Sr(2)N with TiN and characterized by powder X-ray diffraction. SrTiN(2) crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Å, c = 7.6985(4) Å, Z = 2) and is isostructural with KCoO(2). Titanium is coordinated to five nitrogens in a distorted square-based pyramidal geometry, forming layers of edge-sharing pyramids which stack along the (001) direction. Strontium is situated between the Ti-N layers and is coordinated to five nitrogen atoms. The title compound is only the third example of a ternary titanium nitride. |
| spellingShingle | Gregory, D Barker, MG Edwards, P Siddons, D Synthesis and Structure of the New Ternary Nitride SrTiN(2). |
| title | Synthesis and Structure of the New Ternary Nitride SrTiN(2). |
| title_full | Synthesis and Structure of the New Ternary Nitride SrTiN(2). |
| title_fullStr | Synthesis and Structure of the New Ternary Nitride SrTiN(2). |
| title_full_unstemmed | Synthesis and Structure of the New Ternary Nitride SrTiN(2). |
| title_short | Synthesis and Structure of the New Ternary Nitride SrTiN(2). |
| title_sort | synthesis and structure of the new ternary nitride srtin 2 |
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