Synthesis and properties of [NiCp*(2,5-tBu2PC4H2)], a 20-valence-electron phosphanickelocene.

Synthesis and properties of [NiCp*(2,5-tBu2PC4H2)], a 20-valence-electron phosphanickelocene.

The reaction of the bulky phospholide salt Li(2,5-tBu2PC4H2) x 2THF (1; THF = tetrahydrofuran) with [NiCp*(acac)] (HCp* = pentamethylcyclopentadiene, Hacac = acetylacetone) gives the green air-sensitive phosphanickelocene [NiCp*(2,5-tBu2PC4H2)] (2) in yields of about 85%. An X-ray structural determi...

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Bibliographic Details
Main Authors:	Burney, C, Carmichael, D, Forissier, K, Green, J, Mathey, F, Ricard, L
Format:	Journal article
Language:	English
Published:	2005

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