Electronic origins of structural distortions in post-transition metal oxides: experimental and theoretical evidence for a revision of the lone pair model

Electronic origins of structural distortions in post-transition metal oxides: experimental and theoretical evidence for a revision of the lone pair model

Hiển thị phiên bản (1) khác

Structural distortions in post-transition metal oxides are often explained in terms of the influence of s p hybrid "lone pairs". Evidence is presented here showing that this model must be revised. The electronic structures of prototypically distorted α-PbO and α-Bi2O3 have been measured by...

Mô tả đầy đủ

Chi tiết về thư mục
Những tác giả chính:	Payne, D, Egdell, R, Walsh, A, Watson, G, Guo, J, Glans, P, Learmonth, T, Smith, K
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	American Physical Society 2006
Những chủ đề:	Inorganic chemistry Chemistry & allied sciences Physics

Những quyển sách tương tự

Experimental and theoretical study of the electronic structure of HgO and Tl2O3
Bằng: Glans, P, et al.
Được phát hành: (2005)

High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
Bằng: Aston, D, et al.
Được phát hành: (2005)

Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy
Bằng: Payne, D, et al.
Được phát hành: (2007)

Electronic origins of structural distortions in post-transition metal oxides: experimental and theoretical evidence for a revision of the lone pair model.
Bằng: Payne, D, et al.
Được phát hành: (2006)

n-type doping in Cd2SnO4: a study by EELS and photoemission
Bằng: Dou, Y, et al.
Được phát hành: (1996)

Influence of shallow core-level hybridization on the electronic structure of post-transition-metal oxides studied using soft X-ray emission and absorption
Bằng: McGuinness, C, et al.
Được phát hành: (2003)

A study of core and valence levels in β-PbO₂ by hard X-ray photoemission
Bằng: Payne, D, et al.
Được phát hành: (2009)

Band-gap shrinkage in n-type-doped CdO probed by photoemission spectroscopy
Bằng: Dou, Y, et al.
Được phát hành: (1997)

Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission
Bằng: Morris, D, et al.
Được phát hành: (1997)

Ion-pair and anion recognition by macrocycles and interpenetrative assemblies
Bằng: Picot, S
Được phát hành: (2013)

Photoemission and STM study of the electronic structure of Nb-doped TiO2
Bằng: Morris, D, et al.
Được phát hành: (2000)

Direct assignment of EPR spectra to structurally defined iron-sulfur clusters in complex I by double electron-electron resonance
Bằng: Roessler, M, et al.
Được phát hành: (2010)

Anion-templated synthesis of functional interlocked architectures
Bằng: Hancock, L
Được phát hành: (2011)

Solvothermal synthesis of N-doped TiO₂ nanotubes for visible-light-responsive photocatalysis
Bằng: Jiang, Z, et al.
Được phát hành: (2008)

Electrochemical characterisation and application of multi microelectrode array devices to biological electrochemistry
Bằng: Kudera, M, et al.
Được phát hành: (2001)

Studies of ansa-bis(cyclopentadienyl)tungsten derivatives
Bằng: Conway, S, et al.
Được phát hành: (1998)

Synthesis, structure and density functional study of the ansa-rhenocene complex [Re{(η-C5H4)CMe2(η-C5H4)}Cl]
Bằng: Conway, S, et al.
Được phát hành: (2000)

Hydrogen/deuterium exchange in alkyl-hydride derivatives of ansa-tungstenocene compounds
Bằng: Green, M, et al.
Được phát hành: (2005)

Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex
Bằng: Pons, V, et al.
Được phát hành: (2004)

Solution reactivity studies of group 15 Zintl anions towards unsaturated substrates
Bằng: Turbervill, R
Được phát hành: (2014)

Bridging-terminal exchange in ansa-bridged tetrahydroborate niobocene compounds: a density functional study
Bằng: Ashworth, N, et al.
Được phát hành: (2000)

Hydrogen nexus in a sustainable energy future
Bằng: Sartbaeva, A, et al.
Được phát hành: (2008)

Heat capacity measurements on FeAs-based compounds: a thermodynamic probe of electronic and magnetic states
Bằng: Baker, P, et al.
Được phát hành: (2009)

Novel aspects of layered double hydroxide chemistry
Bằng: Markland, C
Được phát hành: (2013)

Structure–reactivity correlations in new W(IV) and Nb(IV) silicon-bridged ansa-metallocene hydrides
Bằng: Conway, S, et al.
Được phát hành: (2006)

Group 5 ansa-metallocenes: Structural and dynamic properties of tetrahydroborate complexes
Bằng: Conway, S, et al.
Được phát hành: (2000)

Synthesis and characterisation of metal oxides isostructural with La(18)Li(8)Rh(5)O(39)
Bằng: Thammajak, N
Được phát hành: (2012)

Synthesis and characterization of WS₂ inorganic nanotubes with encapsulated/intercalated CsI
Bằng: Hong, S, et al.
Được phát hành: (2010)

Imidazolium- and triazolium-based interlocked structures for anion recognition and sensing
Bằng: Spence, G
Được phát hành: (2012)

Photocatalytic water splitting by utilising oxide semiconductor materials
Bằng: Lai, H, et al.
Được phát hành: (2012)

Study of shape effect of Pd promoted Ga2O3 nanocatalysts for methanol synthesis and utilization
Bằng: Zhou, X
Được phát hành: (2013)

Halogen bonding interlocked host systems for recognition and sensing of anions
Bằng: Mullaney, B, et al.
Được phát hành: (2014)

Effect of magnetic fields on cryptochrome-dependent responses in Arabidopsis thaliana
Bằng: Harris, S, et al.
Được phát hành: (2009)

Self-assembly and anion recognition with binuclear lanthanide complexes
Bằng: Thom, J, et al.
Được phát hành: (2014)

Indenyl and diazene chemistry
Bằng: Ransom, P
Được phát hành: (2009)

Competition between initial-and final-state effects in valence- and core-level x-ray photoemission of Sb-doped SnO2
Bằng: Egdell, R, et al.
Được phát hành: (1999)

Stereochemistry of post-transition metal oxides: revision of the classical lone pair model.
Bằng: Walsh, A, et al.
Được phát hành: (2011)

Influence of modifiers on Palladium based nanoparticles for room temperature formic acid decomposition
Bằng: Jones, SP
Được phát hành: (2013)

Reactions of [FeFe]-hydrogenase with carbon monoxide and formaldehyde
Bằng: Foster, C, et al.
Được phát hành: (2012)

Chemical reactivity of group 14 [E9]4– and 15 [E'7]3– Zintl ions
Bằng: Espinoza Quintero, G
Được phát hành: (2015)