Electronic origins of structural distortions in post-transition metal oxides: experimental and theoretical evidence for a revision of the lone pair model

Structural distortions in post-transition metal oxides are often explained in terms of the influence of s p hybrid "lone pairs". Evidence is presented here showing that this model must be revised. The electronic structures of prototypically distorted α-PbO and α-Bi2O3 have been measured by...

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Main Authors: Payne, D, Egdell, R, Walsh, A, Watson, G, Guo, J, Glans, P, Learmonth, T, Smith, K
格式: Journal article
語言:English
出版: American Physical Society 2006
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