Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes
Disodium ethylene-bis-hexamethylindenyl, {(C9Me6)2C2H4}Na2 (EBI*Na2), has been prepared in good yield by the reaction of lithium heptamethylindenyl with cyanogen bromide followed by treatment with sodium naphthalenide. EBI*Na2 reacts with anhydrous Co(acac)2 to give a mixture of rac and meso-ethylen...
| Huvudupphovsmän: | , , , |
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| Materialtyp: | Journal article |
| Språk: | English |
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2009
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| _version_ | 1826299845928812544 |
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| author | Ransom, P Ashley, A Thompson, A O'Hare, D |
| author_facet | Ransom, P Ashley, A Thompson, A O'Hare, D |
| author_sort | Ransom, P |
| collection | OXFORD |
| description | Disodium ethylene-bis-hexamethylindenyl, {(C9Me6)2C2H4}Na2 (EBI*Na2), has been prepared in good yield by the reaction of lithium heptamethylindenyl with cyanogen bromide followed by treatment with sodium naphthalenide. EBI*Na2 reacts with anhydrous Co(acac)2 to give a mixture of rac and meso-ethylene-bis-hexamethylindenyl cobalt(II) (EBI*Co). The isomers can be separated by fractional crystallisation and the rac-isomer has been structurally characterised. Oxidation of the reaction mixture yields both rac and meso-ethylene-bis-hexamethylindenyl cobalt(III) which have both been structurally characterised. © 2008 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-07T05:08:10Z |
| format | Journal article |
| id | oxford-uuid:daa56cc7-58ae-4ac5-8bc3-0e55bddac2a0 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:08:10Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:daa56cc7-58ae-4ac5-8bc3-0e55bddac2a02022-03-27T09:04:40ZSynthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:daa56cc7-58ae-4ac5-8bc3-0e55bddac2a0EnglishSymplectic Elements at Oxford2009Ransom, PAshley, AThompson, AO'Hare, DDisodium ethylene-bis-hexamethylindenyl, {(C9Me6)2C2H4}Na2 (EBI*Na2), has been prepared in good yield by the reaction of lithium heptamethylindenyl with cyanogen bromide followed by treatment with sodium naphthalenide. EBI*Na2 reacts with anhydrous Co(acac)2 to give a mixture of rac and meso-ethylene-bis-hexamethylindenyl cobalt(II) (EBI*Co). The isomers can be separated by fractional crystallisation and the rac-isomer has been structurally characterised. Oxidation of the reaction mixture yields both rac and meso-ethylene-bis-hexamethylindenyl cobalt(III) which have both been structurally characterised. © 2008 Elsevier B.V. All rights reserved. |
| spellingShingle | Ransom, P Ashley, A Thompson, A O'Hare, D Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes |
| title | Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes |
| title_full | Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes |
| title_fullStr | Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes |
| title_full_unstemmed | Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes |
| title_short | Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes |
| title_sort | synthesis structure and characterisation of rac and meso ansa bridged permethylindenyl cobalt complexes |
| work_keys_str_mv | AT ransomp synthesisstructureandcharacterisationofracandmesoansabridgedpermethylindenylcobaltcomplexes AT ashleya synthesisstructureandcharacterisationofracandmesoansabridgedpermethylindenylcobaltcomplexes AT thompsona synthesisstructureandcharacterisationofracandmesoansabridgedpermethylindenylcobaltcomplexes AT ohared synthesisstructureandcharacterisationofracandmesoansabridgedpermethylindenylcobaltcomplexes |