Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence

A europium complex derived from NP-(DO3A)2 exhibits pHdependent europium-centred luminescence following excitation of the nitrophenolate chromophore. Such behaviour is not observed with an analogous mononuclear complex, suggesting coordination of both lanthanide ions to the phenolate oxygen in the...

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Main Authors: Faulkner, S, Blackburn, O, Tropiano, M, Kenwright, A, Natrajan, L
Format: Journal article
Published: Royal Society of Chemistry 2016
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author Faulkner, S
Blackburn, O
Tropiano, M
Kenwright, A
Natrajan, L
author_facet Faulkner, S
Blackburn, O
Tropiano, M
Kenwright, A
Natrajan, L
author_sort Faulkner, S
collection OXFORD
description A europium complex derived from NP-(DO3A)2 exhibits pHdependent europium-centred luminescence following excitation of the nitrophenolate chromophore. Such behaviour is not observed with an analogous mononuclear complex, suggesting coordination of both lanthanide ions to the phenolate oxygen in the emissive species.
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spelling oxford-uuid:dbd1a1b9-05d2-4459-aeb3-f88ee13d695a2022-03-27T09:13:26ZLuminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependenceJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:dbd1a1b9-05d2-4459-aeb3-f88ee13d695aSymplectic Elements at OxfordRoyal Society of Chemistry2016Faulkner, SBlackburn, OTropiano, MKenwright, ANatrajan, LA europium complex derived from NP-(DO3A)2 exhibits pHdependent europium-centred luminescence following excitation of the nitrophenolate chromophore. Such behaviour is not observed with an analogous mononuclear complex, suggesting coordination of both lanthanide ions to the phenolate oxygen in the emissive species.
spellingShingle Faulkner, S
Blackburn, O
Tropiano, M
Kenwright, A
Natrajan, L
Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence
title Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence
title_full Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence
title_fullStr Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence
title_full_unstemmed Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence
title_short Luminescence of a binuclear europium complex bearing a 4-nitrophenolate chromophore: a different way of seeing pH dependence
title_sort luminescence of a binuclear europium complex bearing a 4 nitrophenolate chromophore a different way of seeing ph dependence
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AT blackburno luminescenceofabinucleareuropiumcomplexbearinga4nitrophenolatechromophoreadifferentwayofseeingphdependence
AT tropianom luminescenceofabinucleareuropiumcomplexbearinga4nitrophenolatechromophoreadifferentwayofseeingphdependence
AT kenwrighta luminescenceofabinucleareuropiumcomplexbearinga4nitrophenolatechromophoreadifferentwayofseeingphdependence
AT natrajanl luminescenceofabinucleareuropiumcomplexbearinga4nitrophenolatechromophoreadifferentwayofseeingphdependence