Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.
Square-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.
| Main Authors: | , , , , , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2012
|
| _version_ | 1797098683701919744 |
|---|---|
| author | Manson, J Woods, T Lapidus, S Stephens, P Southerland, H Zapf, V Singleton, J Goddard, P Lancaster, T Steele, A Blundell, S |
| author_facet | Manson, J Woods, T Lapidus, S Stephens, P Southerland, H Zapf, V Singleton, J Goddard, P Lancaster, T Steele, A Blundell, S |
| author_sort | Manson, J |
| collection | OXFORD |
| description | Square-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction. |
| first_indexed | 2024-03-07T05:13:06Z |
| format | Journal article |
| id | oxford-uuid:dc3e5aa5-daec-4894-aeda-bd4d64baa191 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:13:06Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:dc3e5aa5-daec-4894-aeda-bd4d64baa1912022-03-27T09:16:23ZAg(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:dc3e5aa5-daec-4894-aeda-bd4d64baa191EnglishSymplectic Elements at Oxford2012Manson, JWoods, TLapidus, SStephens, PSoutherland, HZapf, VSingleton, JGoddard, PLancaster, TSteele, ABlundell, SSquare-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction. |
| spellingShingle | Manson, J Woods, T Lapidus, S Stephens, P Southerland, H Zapf, V Singleton, J Goddard, P Lancaster, T Steele, A Blundell, S Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions. |
| title | Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions. |
| title_full | Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions. |
| title_fullStr | Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions. |
| title_full_unstemmed | Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions. |
| title_short | Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions. |
| title_sort | ag nic 2 nic nicotinate a spin canted quasi 2d antiferromagnet composed of square planar s 1 2 ag ii ions |
| work_keys_str_mv | AT mansonj agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT woodst agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT lapiduss agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT stephensp agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT southerlandh agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT zapfv agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT singletonj agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT goddardp agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT lancastert agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT steelea agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions AT blundells agnic2nicnicotinateaspincantedquasi2dantiferromagnetcomposedofsquareplanars12agiiions |