Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.

Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.

Square-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.

Bibliographic Details
Main Authors: Manson, J, Woods, T, Lapidus, S, Stephens, P, Southerland, H, Zapf, V, Singleton, J, Goddard, P, Lancaster, T, Steele, A, Blundell, S
Format: Journal article
Language:English
Published: 2012

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