Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with (AlBu3)-Bu-i

Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with (AlBu3)-Bu-i

A series of alkyl- and aryl-imido titanium dialkyl compounds Ti(N'Bu)(Me3[9]aneN3)R2 (R = Me (1), CH 2SiMe3 (3), CH2tBu (4), CH 2Ph (5)), Ti(NR)(Me3[9]aneN3)Me2 (R = iPr (6), Ph. (7), 3,5-C6H3(CF 3)2 (8), 2,6-C6H3iPr 2 (9), 2-C6H4CF3 (10), 2-C 6H4tBu (11)), and Ti(NR)(Me3[9] aneN3)(CH2SiMe3)2 (...

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Bibliographic Details
Main Authors: Bolton, P, Adams, N, Clot, E, Cowley, A, Wilson, P, Schroeder, M, Mountford, P
Format: Journal article
Language:English
Published: 2006

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