Origin of diastereocontrol in the oxy-Michael reactions of delta-lactol anions: a computational and experimental study.

The diastereoselectivity in the alkylation and Michael addition of "naked" 6-substituted delta-lactolates has been studied by density functional (B3LYP) calculations with ab initio (MP2) energy refinements. The resulting proposed model for the origins of stereocontrol in this reaction has...

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Príomhchruthaitheoirí: Richardson, R, Hernandez-Juan, F, Ward, J, Dixon, D
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2008