Transition metal catalyzed alkene and alkyne hydroacylation.
Several researchers conducted studies to demonstrate metal catalyzed alkene and alkyne hydrocylation. A team of researchers developed a method for the synthesis of cyclooctenones using the intramolecular hydrogenation. Eight-membered ring formation was achieved by the incorporation of a cyclopropane...
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| Format: | Journal article |
| Language: | English |
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2010
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| _version_ | 1797098969165201408 |
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| author | Willis, M |
| author_facet | Willis, M |
| author_sort | Willis, M |
| collection | OXFORD |
| description | Several researchers conducted studies to demonstrate metal catalyzed alkene and alkyne hydrocylation. A team of researchers developed a method for the synthesis of cyclooctenones using the intramolecular hydrogenation. Eight-membered ring formation was achieved by the incorporation of a cyclopropane ring in the substrate to demonstrate metal catalyzed alkene and alkyne hydrocylation. The key step of the method involved the fragmentation and isomerization of rhodacycle 25 into ring-expanded rhodacycle 26. The researchers investigated the reactions of the two isomers of a deuterium-labeled substrate to explore the mechanism in operation. Another team of researchers prepared a series of medium-ring sulfur heterocycles using intramolecular hydroacylation to demonstrate the investigations. |
| first_indexed | 2024-03-07T05:17:07Z |
| format | Journal article |
| id | oxford-uuid:dd988dec-27f4-4f19-93d9-45ed8e0f6cbc |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:17:07Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:dd988dec-27f4-4f19-93d9-45ed8e0f6cbc2022-03-27T09:26:07ZTransition metal catalyzed alkene and alkyne hydroacylation.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:dd988dec-27f4-4f19-93d9-45ed8e0f6cbcEnglishSymplectic Elements at Oxford2010Willis, MSeveral researchers conducted studies to demonstrate metal catalyzed alkene and alkyne hydrocylation. A team of researchers developed a method for the synthesis of cyclooctenones using the intramolecular hydrogenation. Eight-membered ring formation was achieved by the incorporation of a cyclopropane ring in the substrate to demonstrate metal catalyzed alkene and alkyne hydrocylation. The key step of the method involved the fragmentation and isomerization of rhodacycle 25 into ring-expanded rhodacycle 26. The researchers investigated the reactions of the two isomers of a deuterium-labeled substrate to explore the mechanism in operation. Another team of researchers prepared a series of medium-ring sulfur heterocycles using intramolecular hydroacylation to demonstrate the investigations. |
| spellingShingle | Willis, M Transition metal catalyzed alkene and alkyne hydroacylation. |
| title | Transition metal catalyzed alkene and alkyne hydroacylation. |
| title_full | Transition metal catalyzed alkene and alkyne hydroacylation. |
| title_fullStr | Transition metal catalyzed alkene and alkyne hydroacylation. |
| title_full_unstemmed | Transition metal catalyzed alkene and alkyne hydroacylation. |
| title_short | Transition metal catalyzed alkene and alkyne hydroacylation. |
| title_sort | transition metal catalyzed alkene and alkyne hydroacylation |
| work_keys_str_mv | AT willism transitionmetalcatalyzedalkeneandalkynehydroacylation |