A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0)
A dinuclear pyridyl-bridged palladium complex, trans-(P,N)-[PdBr(μ- C5H4N-C2,N)(PPh3)]2 1, was obtained from material isolated from the Suzuki cross-coupling reaction of 2-bromopyridine with 2,4-difluorophenylboronic acid in the presence of catalytic (PPh3)4Pd. Complex 1 is an effective precatalyst...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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| _version_ | 1797099127718281216 |
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| author | Beeby, A Bettington, S Fairlamb, I Goeta, A Kapdi, A Niemela, E Thompson, A |
| author_facet | Beeby, A Bettington, S Fairlamb, I Goeta, A Kapdi, A Niemela, E Thompson, A |
| author_sort | Beeby, A |
| collection | OXFORD |
| description | A dinuclear pyridyl-bridged palladium complex, trans-(P,N)-[PdBr(μ- C5H4N-C2,N)(PPh3)]2 1, was obtained from material isolated from the Suzuki cross-coupling reaction of 2-bromopyridine with 2,4-difluorophenylboronic acid in the presence of catalytic (PPh3)4Pd. Complex 1 is an effective precatalyst for the Suzuki cross-coupling reactions of a variety organoboronic acids and aryl bromides, and represents a useful source of mono-ligated palladium(0), "(Ph3P)Pd(0)". |
| first_indexed | 2024-03-07T05:19:14Z |
| format | Journal article |
| id | oxford-uuid:de4e141a-9304-4a54-a769-7958a0ee0bcb |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:19:14Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:de4e141a-9304-4a54-a769-7958a0ee0bcb2022-03-27T09:31:17ZA new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:de4e141a-9304-4a54-a769-7958a0ee0bcbEnglishSymplectic Elements at Oxford2004Beeby, ABettington, SFairlamb, IGoeta, AKapdi, ANiemela, EThompson, AA dinuclear pyridyl-bridged palladium complex, trans-(P,N)-[PdBr(μ- C5H4N-C2,N)(PPh3)]2 1, was obtained from material isolated from the Suzuki cross-coupling reaction of 2-bromopyridine with 2,4-difluorophenylboronic acid in the presence of catalytic (PPh3)4Pd. Complex 1 is an effective precatalyst for the Suzuki cross-coupling reactions of a variety organoboronic acids and aryl bromides, and represents a useful source of mono-ligated palladium(0), "(Ph3P)Pd(0)". |
| spellingShingle | Beeby, A Bettington, S Fairlamb, I Goeta, A Kapdi, A Niemela, E Thompson, A A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0) |
| title | A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0) |
| title_full | A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0) |
| title_fullStr | A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0) |
| title_full_unstemmed | A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0) |
| title_short | A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0) |
| title_sort | new precatalyst for the suzuki reaction a pyridyl bridged dinuclear palladium complex as a source of mono ligated palladium 0 |
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