Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes.
Unprecedented bicyclic methylene aziridines are prepared by rhodium(II)-catalyzed allene aziridination of buta-2,3-dienyl carbamates. Aspects of their NMR and X-ray data are described and a preliminary reactivity profile is given, including overall S(N)V-mode ring-opening with organometallic reagent...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2010
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| _version_ | 1797099143195262976 |
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| author | Robertson, J Feast, G White, L Steadman, V Claridge, T |
| author_facet | Robertson, J Feast, G White, L Steadman, V Claridge, T |
| author_sort | Robertson, J |
| collection | OXFORD |
| description | Unprecedented bicyclic methylene aziridines are prepared by rhodium(II)-catalyzed allene aziridination of buta-2,3-dienyl carbamates. Aspects of their NMR and X-ray data are described and a preliminary reactivity profile is given, including overall S(N)V-mode ring-opening with organometallic reagents. |
| first_indexed | 2024-03-07T05:19:28Z |
| format | Journal article |
| id | oxford-uuid:de6028ee-5adc-4a1b-9005-a3c31beace53 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:19:28Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:de6028ee-5adc-4a1b-9005-a3c31beace532022-03-27T09:31:50ZStructure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:de6028ee-5adc-4a1b-9005-a3c31beace53EnglishSymplectic Elements at Oxford2010Robertson, JFeast, GWhite, LSteadman, VClaridge, TUnprecedented bicyclic methylene aziridines are prepared by rhodium(II)-catalyzed allene aziridination of buta-2,3-dienyl carbamates. Aspects of their NMR and X-ray data are described and a preliminary reactivity profile is given, including overall S(N)V-mode ring-opening with organometallic reagents. |
| spellingShingle | Robertson, J Feast, G White, L Steadman, V Claridge, T Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes. |
| title | Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes. |
| title_full | Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes. |
| title_fullStr | Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes. |
| title_full_unstemmed | Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes. |
| title_short | Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes. |
| title_sort | structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes |
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