Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids
Efficient synthesis of both cis- and trans-3-azido-oxetane-2-carboxylates relies upon efficient nucleophilic displacements of 3-O-triflates of oxetanes by trifluoroacetate and azide. Such structures are scaffolds for incorporation of oxetane-β-amino acids into oligomers; the synthesis of a series of...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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| _version_ | 1797099156911685632 |
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| author | Barker, S Angus, D Taillefumier, C Probert, MR Watkin, D Watterson, M Claridge, T Hungerford, N Fleet, G |
| author_facet | Barker, S Angus, D Taillefumier, C Probert, MR Watkin, D Watterson, M Claridge, T Hungerford, N Fleet, G |
| author_sort | Barker, S |
| collection | OXFORD |
| description | Efficient synthesis of both cis- and trans-3-azido-oxetane-2-carboxylates relies upon efficient nucleophilic displacements of 3-O-triflates of oxetanes by trifluoroacetate and azide. Such structures are scaffolds for incorporation of oxetane-β-amino acids into oligomers; the synthesis of a series of protected β-hexapeptides and the X-ray crystal structure of methyl 2,4-anhydro-6-deoxy-5-O-benzyl-L-altronate are reported. © 2001 Elsevier Science Ltd. |
| first_indexed | 2024-03-07T05:19:40Z |
| format | Journal article |
| id | oxford-uuid:de6fd8ed-2e9c-4b22-b290-b3024926f1f4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:19:40Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:de6fd8ed-2e9c-4b22-b290-b3024926f1f42022-03-27T09:32:17ZCis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acidsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:de6fd8ed-2e9c-4b22-b290-b3024926f1f4EnglishSymplectic Elements at Oxford2001Barker, SAngus, DTaillefumier, CProbert, MRWatkin, DWatterson, MClaridge, THungerford, NFleet, GEfficient synthesis of both cis- and trans-3-azido-oxetane-2-carboxylates relies upon efficient nucleophilic displacements of 3-O-triflates of oxetanes by trifluoroacetate and azide. Such structures are scaffolds for incorporation of oxetane-β-amino acids into oligomers; the synthesis of a series of protected β-hexapeptides and the X-ray crystal structure of methyl 2,4-anhydro-6-deoxy-5-O-benzyl-L-altronate are reported. © 2001 Elsevier Science Ltd. |
| spellingShingle | Barker, S Angus, D Taillefumier, C Probert, MR Watkin, D Watterson, M Claridge, T Hungerford, N Fleet, G Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids |
| title | Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids |
| title_full | Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids |
| title_fullStr | Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids |
| title_full_unstemmed | Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids |
| title_short | Cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: hexamers of oxetane cis-beta-amino acids |
| title_sort | cis and trans 3 azido oxetane 2 carboxylate scaffolds hexamers of oxetane cis beta amino acids |
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