Thermally stable perovskite solar cells by all-vacuum deposition
<p>Vacuum deposition is a solvent-free method suitable for growing thin films of metal halide perovskite (MHP) semiconductors. However, most reports of high-efficiency solar cells based on such vacuum-deposited MHP films i...
| Үндсэн зохиолчид: | , , , , , , , , , , |
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| Формат: | Journal article |
| Хэл сонгох: | English |
| Хэвлэсэн: |
American Chemical Society
2022
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| _version_ | 1826309232507486208 |
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| author | Yuan, Q Lohmann, KB Oliver, RDJ Ramadan, AJ Yan, S Ball, JM Christoforo, MG Noel, NK Snaith, HJ Herz, LM Johnston, M |
| author_facet | Yuan, Q Lohmann, KB Oliver, RDJ Ramadan, AJ Yan, S Ball, JM Christoforo, MG Noel, NK Snaith, HJ Herz, LM Johnston, M |
| author_sort | Yuan, Q |
| collection | OXFORD |
| description | <p>Vacuum deposition is a solvent-free method suitable for growing thin films of metal halide perovskite (MHP) semiconductors. However, most reports of high-efficiency solar cells based on such vacuum-deposited MHP films incorporate solution-processed hole transport layers (HTLs), thereby complicating prospects of industrial upscaling and potentially affecting the overall device stability. In this work, we investigate organometallic copper phthalocyanine (CuPc) and zinc phthalocyanine (ZnPc) as alternative, low-cost, and durable HTLs in all-vacuum-deposited solvent-free formamidinium-cesium lead triodide [CH(NH<sub>2</sub>)<sub>2</sub>]<sub>0.83</sub>Cs<sub>0.17</sub>PbI<sub>3</sub> (FACsPbI<sub>3</sub>) perovskite solar cells. We elucidate that the CuPc HTL, when employed in an “inverted” p–i–n solar cell configuration, attains a solar-to-electrical power conversion efficiency of up to 13.9%. Importantly, unencapsulated devices as large as 1 cm<sup>2</sup> exhibited excellent long-term stability, demonstrating no observable degradation in efficiency after more than 5000 h in storage and 3700 h under 85 °C thermal stressing in N<sub>2</sub> atmosphere.</p> |
| first_indexed | 2024-03-07T07:31:03Z |
| format | Journal article |
| id | oxford-uuid:de7552a6-3e8b-402e-bfdc-f25c6dd2f7c3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:31:03Z |
| publishDate | 2022 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:de7552a6-3e8b-402e-bfdc-f25c6dd2f7c32023-01-20T09:58:25ZThermally stable perovskite solar cells by all-vacuum depositionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:de7552a6-3e8b-402e-bfdc-f25c6dd2f7c3EnglishSymplectic ElementsAmerican Chemical Society2022Yuan, QLohmann, KBOliver, RDJRamadan, AJYan, SBall, JMChristoforo, MGNoel, NKSnaith, HJHerz, LMJohnston, M<p>Vacuum deposition is a solvent-free method suitable for growing thin films of metal halide perovskite (MHP) semiconductors. However, most reports of high-efficiency solar cells based on such vacuum-deposited MHP films incorporate solution-processed hole transport layers (HTLs), thereby complicating prospects of industrial upscaling and potentially affecting the overall device stability. In this work, we investigate organometallic copper phthalocyanine (CuPc) and zinc phthalocyanine (ZnPc) as alternative, low-cost, and durable HTLs in all-vacuum-deposited solvent-free formamidinium-cesium lead triodide [CH(NH<sub>2</sub>)<sub>2</sub>]<sub>0.83</sub>Cs<sub>0.17</sub>PbI<sub>3</sub> (FACsPbI<sub>3</sub>) perovskite solar cells. We elucidate that the CuPc HTL, when employed in an “inverted” p–i–n solar cell configuration, attains a solar-to-electrical power conversion efficiency of up to 13.9%. Importantly, unencapsulated devices as large as 1 cm<sup>2</sup> exhibited excellent long-term stability, demonstrating no observable degradation in efficiency after more than 5000 h in storage and 3700 h under 85 °C thermal stressing in N<sub>2</sub> atmosphere.</p> |
| spellingShingle | Yuan, Q Lohmann, KB Oliver, RDJ Ramadan, AJ Yan, S Ball, JM Christoforo, MG Noel, NK Snaith, HJ Herz, LM Johnston, M Thermally stable perovskite solar cells by all-vacuum deposition |
| title | Thermally stable perovskite solar cells by all-vacuum deposition |
| title_full | Thermally stable perovskite solar cells by all-vacuum deposition |
| title_fullStr | Thermally stable perovskite solar cells by all-vacuum deposition |
| title_full_unstemmed | Thermally stable perovskite solar cells by all-vacuum deposition |
| title_short | Thermally stable perovskite solar cells by all-vacuum deposition |
| title_sort | thermally stable perovskite solar cells by all vacuum deposition |
| work_keys_str_mv | AT yuanq thermallystableperovskitesolarcellsbyallvacuumdeposition AT lohmannkb thermallystableperovskitesolarcellsbyallvacuumdeposition AT oliverrdj thermallystableperovskitesolarcellsbyallvacuumdeposition AT ramadanaj thermallystableperovskitesolarcellsbyallvacuumdeposition AT yans thermallystableperovskitesolarcellsbyallvacuumdeposition AT balljm thermallystableperovskitesolarcellsbyallvacuumdeposition AT christoforomg thermallystableperovskitesolarcellsbyallvacuumdeposition AT noelnk thermallystableperovskitesolarcellsbyallvacuumdeposition AT snaithhj thermallystableperovskitesolarcellsbyallvacuumdeposition AT herzlm thermallystableperovskitesolarcellsbyallvacuumdeposition AT johnstonm thermallystableperovskitesolarcellsbyallvacuumdeposition |