Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy.
(Chemical Equation Presented) Rh steps into the ring: The radical cation shown is best described as a rhodaazacyclopropane (A) rather than as a Rh I iminium ion complex (B). EPR and DFT data indicate that the delocalization of the unpaired electron into the ligand framework contributes to the stabil...
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Bibliographic Details
Main Authors: |
Maire, P,
Sreekanth, A,
Büttner, T,
Harmer, J,
Gromov, I,
Rüegger, H,
Breher, F,
Schweiger, A,
Grützmacher, H |
Format: | Journal article
|
Language: | English |
Published: |
2006
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