Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy.
(Chemical Equation Presented) Rh steps into the ring: The radical cation shown is best described as a rhodaazacyclopropane (A) rather than as a Rh I iminium ion complex (B). EPR and DFT data indicate that the delocalization of the unpaired electron into the ligand framework contributes to the stabil...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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| _version_ | 1797099221179957248 |
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| author | Maire, P Sreekanth, A Büttner, T Harmer, J Gromov, I Rüegger, H Breher, F Schweiger, A Grützmacher, H |
| author_facet | Maire, P Sreekanth, A Büttner, T Harmer, J Gromov, I Rüegger, H Breher, F Schweiger, A Grützmacher, H |
| author_sort | Maire, P |
| collection | OXFORD |
| description | (Chemical Equation Presented) Rh steps into the ring: The radical cation shown is best described as a rhodaazacyclopropane (A) rather than as a Rh I iminium ion complex (B). EPR and DFT data indicate that the delocalization of the unpaired electron into the ligand framework contributes to the stability of A (see plot of the singly occupied molecular orbital). © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T05:20:38Z |
| format | Journal article |
| id | oxford-uuid:dec6468a-09b7-4606-a1f7-27c8a2df19f8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:20:38Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:dec6468a-09b7-4606-a1f7-27c8a2df19f82022-03-27T09:34:37ZSynthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:dec6468a-09b7-4606-a1f7-27c8a2df19f8EnglishSymplectic Elements at Oxford2006Maire, PSreekanth, ABüttner, THarmer, JGromov, IRüegger, HBreher, FSchweiger, AGrützmacher, H(Chemical Equation Presented) Rh steps into the ring: The radical cation shown is best described as a rhodaazacyclopropane (A) rather than as a Rh I iminium ion complex (B). EPR and DFT data indicate that the delocalization of the unpaired electron into the ligand framework contributes to the stability of A (see plot of the singly occupied molecular orbital). © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Maire, P Sreekanth, A Büttner, T Harmer, J Gromov, I Rüegger, H Breher, F Schweiger, A Grützmacher, H Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy. |
| title | Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy. |
| title_full | Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy. |
| title_fullStr | Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy. |
| title_full_unstemmed | Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy. |
| title_short | Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy. |
| title_sort | synthesis of a rhodaazacyclopropane and characterization of its radical cation by epr spectroscopy |
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