Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy.
(Chemical Equation Presented) Rh steps into the ring: The radical cation shown is best described as a rhodaazacyclopropane (A) rather than as a Rh I iminium ion complex (B). EPR and DFT data indicate that the delocalization of the unpaired electron into the ligand framework contributes to the stabil...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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