Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation

<p>Readily available β-carbonyl-substituted aldehydes are shown to be exceptional substrates for Rh-catalyzed intermolecular alkene and alkyne hydroacylation reactions. By using cationic rhodium catalysts incorporating <i>bis</i>-phosphine ligands efficient and selective reactions...

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Príomhchruthaitheoirí: Coxon, TJ, Fernández, M, Barwick-Silk, J, Mckay, AI, Britton, LE, Weller, AS, Willis, M
Formáid: Journal article
Foilsithe / Cruthaithe: American Chemical Society 2017