O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
Combining α-methylthiomethyl (MTM) ether substituted aldehydes and 1-alkynes in the presence of [Rh(dppe)]ClO(4) results in efficient intermolecular alkyne hydroacylation to deliver α-O-MTM-substituted enone products. The product MTM ethers can be converted to the free hydroxyl group either in situ,...
| Главные авторы: | , , |
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| Формат: | Journal article |
| Язык: | English |
| Опубликовано: |
2011
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| _version_ | 1826300829932453888 |
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| author | Parsons, SR Hooper, J Willis, M |
| author_facet | Parsons, SR Hooper, J Willis, M |
| author_sort | Parsons, SR |
| collection | OXFORD |
| description | Combining α-methylthiomethyl (MTM) ether substituted aldehydes and 1-alkynes in the presence of [Rh(dppe)]ClO(4) results in efficient intermolecular alkyne hydroacylation to deliver α-O-MTM-substituted enone products. The product MTM ethers can be converted to the free hydroxyl group either in situ, by the addition of water to the completed reaction, or in a separate operation, by the action of silver nitrate. |
| first_indexed | 2024-03-07T05:23:06Z |
| format | Journal article |
| id | oxford-uuid:df9c17d5-6dd1-4584-9628-1e5f653a59e2 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:23:06Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:df9c17d5-6dd1-4584-9628-1e5f653a59e22022-03-27T09:40:35ZO-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:df9c17d5-6dd1-4584-9628-1e5f653a59e2EnglishSymplectic Elements at Oxford2011Parsons, SRHooper, JWillis, MCombining α-methylthiomethyl (MTM) ether substituted aldehydes and 1-alkynes in the presence of [Rh(dppe)]ClO(4) results in efficient intermolecular alkyne hydroacylation to deliver α-O-MTM-substituted enone products. The product MTM ethers can be converted to the free hydroxyl group either in situ, by the addition of water to the completed reaction, or in a separate operation, by the action of silver nitrate. |
| spellingShingle | Parsons, SR Hooper, J Willis, M O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. |
| title | O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. |
| title_full | O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. |
| title_fullStr | O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. |
| title_full_unstemmed | O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. |
| title_short | O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. |
| title_sort | o substituted alkyl aldehydes for rhodium catalyzed intermolecular alkyne hydroacylation the utility of methylthiomethyl ethers |
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