O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
Combining α-methylthiomethyl (MTM) ether substituted aldehydes and 1-alkynes in the presence of [Rh(dppe)]ClO(4) results in efficient intermolecular alkyne hydroacylation to deliver α-O-MTM-substituted enone products. The product MTM ethers can be converted to the free hydroxyl group either in situ,...
Váldodahkkit: | Parsons, SR, Hooper, J, Willis, M |
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Materiálatiipa: | Journal article |
Giella: | English |
Almmustuhtton: |
2011
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Geahča maid
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