O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.

Combining α-methylthiomethyl (MTM) ether substituted aldehydes and 1-alkynes in the presence of [Rh(dppe)]ClO(4) results in efficient intermolecular alkyne hydroacylation to deliver α-O-MTM-substituted enone products. The product MTM ethers can be converted to the free hydroxyl group either in situ,...

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Bibliográfalaš dieđut
Váldodahkkit: Parsons, SR, Hooper, J, Willis, M
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2011

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