Stereochemistry of post-transition metal oxides: revision of the classical lone pair model.

Stereochemistry of post-transition metal oxides: revision of the classical lone pair model.

The chemistry of post transition metals is dominated by the group oxidation state N and a lower N-2 oxidation state, which is associated with occupation of a metal s(2) lone pair, as found in compounds of Tl(I), Pb(II) and Bi(III). The preference of these cations for non-centrosymmetric coordination...

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Bibliografiske detaljer
Main Authors:	Walsh, A, Payne, D, Egdell, R, Watson, G
Format:	Journal article
Sprog:	English
Udgivet:	2011

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