Asymmetric synthesis of a rigid diphosphine ligand containing two phosphorus and four carbon stereogenic centres by means of a chiral palladium complex promoted Diels-Alder reaction
An optically pure diphosphine ligand containing two phosphorus and four carbon stereogenic centres is prepared efficiently by a chiral organopalladium complex promoted asymmetric Diels-Alder reaction between phenyldi[(Z)-prop-1-enyl]phosphine and 1-phenyl-3,4-dimethylphosphole.
Bibliographic Details
Main Authors: |
Leung, P,
Selvaratnam, S,
Cheng, C,
Mok, K,
Rees, N,
McFarlane, W |
Format: | Journal article
|
Language: | English |
Published: |
1997
|