Asymmetric synthesis of a rigid diphosphine ligand containing two phosphorus and four carbon stereogenic centres by means of a chiral palladium complex promoted Diels-Alder reaction
An optically pure diphosphine ligand containing two phosphorus and four carbon stereogenic centres is prepared efficiently by a chiral organopalladium complex promoted asymmetric Diels-Alder reaction between phenyldi[(Z)-prop-1-enyl]phosphine and 1-phenyl-3,4-dimethylphosphole.
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1997
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