THE STEREOCHEMISTRY OF THE O(1D)+N2O-]NO+NO REACTION VIA VELOCITY-ALIGNED PHOTOFRAGMENT DYNAMICS

Velocity-aligned, superthermal O(1D) atoms generated via the photodissociation of N2O have been employed to investigate the stereodynamics of the title reaction. The power of this experimental technique, when coupled with Doppler-resolved, polarized laser-induced fluorescence probing of the reaction...

תיאור מלא

מידע ביבליוגרפי
Main Authors: Brouard, M, Duxon, S, Enriquez, P, Simons, J
פורמט: Journal article
שפה:English
יצא לאור: 1992
תיאור
סיכום:Velocity-aligned, superthermal O(1D) atoms generated via the photodissociation of N2O have been employed to investigate the stereodynamics of the title reaction. The power of this experimental technique, when coupled with Doppler-resolved, polarized laser-induced fluorescence probing of the reaction products, is demonstrated by reference to the specific reaction channel leading to NO(v′=0)+NO(v′=16,17), which is shown to proceed via direct stripping dynamics. Furthermore, the observed product-state selective linear and angular momenta disposals imply that the reaction is stereodynamically constrained to occur via collinear collision geometries. © 1992 American Institute of Physics.