Asymmetric synthesis of beta-haloaryl beta-amino acid derivatives

Asymmetric synthesis of beta-haloaryl beta-amino acid derivatives

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Lithium N-benzyl-N-α-methyl-4-methoxybenzylamide may be employed as a homochiral ammonia equivalent for the synthesis of homochiral β-haloaryl β-amino acid derivatives via a strategy involving its conjugate addition to α,β-unsaturated β-haloaryl acceptors and subsequent oxidative deprotection with c...

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Príomhchruthaitheoirí: Bull, S, Davies, S, Delgado-Ballester, S, Kelly, P, Kotchie, L, Gianotti, M, Laderas, M, Smith, A
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2001
Cur síos
Achoimre:Lithium N-benzyl-N-α-methyl-4-methoxybenzylamide may be employed as a homochiral ammonia equivalent for the synthesis of homochiral β-haloaryl β-amino acid derivatives via a strategy involving its conjugate addition to α,β-unsaturated β-haloaryl acceptors and subsequent oxidative deprotection with ceric ammonium nitrate.

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