Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4).

Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4).

We report the reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4, [Zn(Im)(2)]). This occurs irrespective of pore occupancy and takes place via a novel high pressure phase (ZIF-4-I) when solvent molecules are present in the pores. A significant reduction in bulk modu...

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Bibliographic Details
Main Authors:	Bennett, T, Simoncic, P, Moggach, SA, Gozzo, F, Macchi, P, Keen, D, Tan, J, Cheetham, A
Format:	Journal article
Language:	English
Published:	2011

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