Photocatalytic three-component umpolung synthesis of 1,3-diamines

A visible-light-mediated photocatalytic umpolung synthesis of 1,3-diamines from in situ-generated imines and dehydroalanine derivatives is described. Pivoting on a key nucleophilic addition of photocatalytically generated α-amino radicals to electron-deficient alkenes, this three-component coupling...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron: Rossolini, T, Leitch, J, Grainger, R, Dixon, D
Fformat: Journal article
Iaith:English
Cyhoeddwyd: American Chemical Society 2018