Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon

In this work, we demonstrate a form of minority carrier degradation on n-type Cz silicon that affects both the bulk and surface related lifetimes. We identify three key behaviors of the degradation mechanism; 1) a firing dependence for the extent of degradation, 2) the appearance of bulk degradation...

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Main Authors: Chen, D, Hamer, PG, Kim, M, Fung, TH, Bourret-Sicotte, G, Liu, S, Chan, CE, Ciesla, A, Chen, R, Abbott, MD, Hallam, BJ, Wenham, SR
Format: Journal article
Published: Elsevier 2018
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author Chen, D
Hamer, PG
Kim, M
Fung, TH
Bourret-Sicotte, G
Liu, S
Chan, CE
Ciesla, A
Chen, R
Abbott, MD
Hallam, BJ
Wenham, SR
author_facet Chen, D
Hamer, PG
Kim, M
Fung, TH
Bourret-Sicotte, G
Liu, S
Chan, CE
Ciesla, A
Chen, R
Abbott, MD
Hallam, BJ
Wenham, SR
author_sort Chen, D
collection OXFORD
description In this work, we demonstrate a form of minority carrier degradation on n-type Cz silicon that affects both the bulk and surface related lifetimes. We identify three key behaviors of the degradation mechanism; 1) a firing dependence for the extent of degradation, 2) the appearance of bulk degradation when wafers are fired in the presence of a diffused emitter and 3) a firing related apparent surface degradation when wafers are fired in the absence of an emitter. We further report a defect capture cross-section ratio of σn/σp = 0.028 ± 0.003 for the defect in n-type. Utilizing our understanding of light and elevated temperature induced degradation (LeTID) in p-type silicon, we demonstrate that the degradation behaviors in both n-type and p-type silicon are closely correlated. In light of numerous reports on the involvement of hydrogen, the potential role of a hydrogen-induced degradation mechanism is discussed in both p- and n-type silicon, particularly in relation to the diffusion of hydrogen and influence of hydrogen-dopant interactions.
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spelling oxford-uuid:e468f21e-dc3d-4a84-a28d-82452aa103f12022-03-27T10:16:28ZHydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type siliconJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e468f21e-dc3d-4a84-a28d-82452aa103f1Symplectic Elements at OxfordElsevier2018Chen, DHamer, PGKim, MFung, THBourret-Sicotte, GLiu, SChan, CECiesla, AChen, RAbbott, MDHallam, BJWenham, SRIn this work, we demonstrate a form of minority carrier degradation on n-type Cz silicon that affects both the bulk and surface related lifetimes. We identify three key behaviors of the degradation mechanism; 1) a firing dependence for the extent of degradation, 2) the appearance of bulk degradation when wafers are fired in the presence of a diffused emitter and 3) a firing related apparent surface degradation when wafers are fired in the absence of an emitter. We further report a defect capture cross-section ratio of σn/σp = 0.028 ± 0.003 for the defect in n-type. Utilizing our understanding of light and elevated temperature induced degradation (LeTID) in p-type silicon, we demonstrate that the degradation behaviors in both n-type and p-type silicon are closely correlated. In light of numerous reports on the involvement of hydrogen, the potential role of a hydrogen-induced degradation mechanism is discussed in both p- and n-type silicon, particularly in relation to the diffusion of hydrogen and influence of hydrogen-dopant interactions.
spellingShingle Chen, D
Hamer, PG
Kim, M
Fung, TH
Bourret-Sicotte, G
Liu, S
Chan, CE
Ciesla, A
Chen, R
Abbott, MD
Hallam, BJ
Wenham, SR
Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon
title Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon
title_full Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon
title_fullStr Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon
title_full_unstemmed Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon
title_short Hydrogen induced degradation: a possible mechanism for light- and elevated temperature- induced degradation in n-type silicon
title_sort hydrogen induced degradation a possible mechanism for light and elevated temperature induced degradation in n type silicon
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