A re-evaluation of the two-step spin crossover in the trinuclear cation [Co3(dipyridylamido)4Cl2]+.

A re-evaluation of the two-step spin crossover in the trinuclear cation [Co3(dipyridylamido)4Cl2]+.

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Density functional theory is used to explore the electronic states involved in the remarkable two-step spin crossover (S = 0 --> S = 1 --> S = 2) in the cationic extended metal atom chain [Co(3)(dpa)(4)Cl(2)](+) (dpa = the anion of 2-dipyridylamine) (R. Clérac, F. A. Cotton, K. R. Dunb...

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Bibliographic Details
Main Authors:	Pantazis, D, Murillo, C, McGrady, J
Format:	Journal article
Language:	English
Published:	2008

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