Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10]
A new uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10] has been synthesized by a hydrothermal reaction technique using (C2H5)4NBr, UO2(OCOCH3)2·2H2O, and HF as reagents. The structure of [N(C2H5)4]2[(UO2)4(OH2)3F10] has been determined by a single-crystal X-ray diffraction technique. [N(C2H5)4]2[(UO...
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| Format: | Journal article |
| Language: | English |
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2007
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| _version_ | 1797100495909683200 |
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| author | Ok, K O'Hare, D |
| author_facet | Ok, K O'Hare, D |
| author_sort | Ok, K |
| collection | OXFORD |
| description | A new uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10] has been synthesized by a hydrothermal reaction technique using (C2H5)4NBr, UO2(OCOCH3)2·2H2O, and HF as reagents. The structure of [N(C2H5)4]2[(UO2)4(OH2)3F10] has been determined by a single-crystal X-ray diffraction technique. [N(C2H5)4]2[(UO2)4(OH2)3F10] crystallizes in the monoclinic space group P21/n (No. 14), with a = 13.852 (3) Å, b = 15.532 (3) Å, c = 16.481 (3) Å, β = 98.88 (3) °, V = 3503.4 (12) Å3, and Z = 4. [N(C2H5)4]2[(UO2)4(OH2)3F10] reveals a novel pseudo-two-dimensional crystal structure that is composed of UO2F5, UO3F4, and UO4F3 pentagonal bipyramids. Each uranyl pentagonal bipyramid shares edges and corners through F atoms to form a six-membered ring. The rings are further interconnected to generate infinite strips running along the b-axis. [N(C2H5)4]2[(UO2)4(OH2)3F10] has been further characterized by elemental analysis, bond valence calculations, Infrared and Raman spectroscopy, and thermogravimetric analysis. © 2006 Elsevier Inc. All rights reserved. |
| first_indexed | 2024-03-07T05:38:21Z |
| format | Journal article |
| id | oxford-uuid:e4b4414c-713a-4f3a-9109-554be418e584 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:38:21Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:e4b4414c-713a-4f3a-9109-554be418e5842022-03-27T10:18:30ZHydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e4b4414c-713a-4f3a-9109-554be418e584EnglishSymplectic Elements at Oxford2007Ok, KO'Hare, DA new uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10] has been synthesized by a hydrothermal reaction technique using (C2H5)4NBr, UO2(OCOCH3)2·2H2O, and HF as reagents. The structure of [N(C2H5)4]2[(UO2)4(OH2)3F10] has been determined by a single-crystal X-ray diffraction technique. [N(C2H5)4]2[(UO2)4(OH2)3F10] crystallizes in the monoclinic space group P21/n (No. 14), with a = 13.852 (3) Å, b = 15.532 (3) Å, c = 16.481 (3) Å, β = 98.88 (3) °, V = 3503.4 (12) Å3, and Z = 4. [N(C2H5)4]2[(UO2)4(OH2)3F10] reveals a novel pseudo-two-dimensional crystal structure that is composed of UO2F5, UO3F4, and UO4F3 pentagonal bipyramids. Each uranyl pentagonal bipyramid shares edges and corners through F atoms to form a six-membered ring. The rings are further interconnected to generate infinite strips running along the b-axis. [N(C2H5)4]2[(UO2)4(OH2)3F10] has been further characterized by elemental analysis, bond valence calculations, Infrared and Raman spectroscopy, and thermogravimetric analysis. © 2006 Elsevier Inc. All rights reserved. |
| spellingShingle | Ok, K O'Hare, D Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10] |
| title | Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10] |
| title_full | Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10] |
| title_fullStr | Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10] |
| title_full_unstemmed | Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10] |
| title_short | Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)(4)](2)[(UO2)(4)(OH2)(3)F-10] |
| title_sort | hydrothermal synthesis crystal structure and characterization of a new pseudo two dimensional uranyl oxyfluoride n c2h5 4 2 uo2 4 oh2 3 f 10 |
| work_keys_str_mv | AT okk hydrothermalsynthesiscrystalstructureandcharacterizationofanewpseudotwodimensionaluranyloxyfluoridenc2h542uo24oh23f10 AT ohared hydrothermalsynthesiscrystalstructureandcharacterizationofanewpseudotwodimensionaluranyloxyfluoridenc2h542uo24oh23f10 |