Titanium Imido Complexes Supported by Amidinate Ligands: Synthesis, Solution Dynamics, and Solid State Structures.
Reaction of Li[PhC(NSiMe(3))(2)] with the complexes [Ti(NR)Cl(2)(py)(3)] affords the corresponding (N,N'-bis(trimethylsilyl)benzamidinato)titanium imido derivatives [Ti(NR){PhC(NSiMe(3))(2)}Cl(py)(2)] [R = Bu(t) (1), 2,6-C(6)H(3)Me(2) (2), 2,6-C(6)H(3)Pr(i)(2) (3)], which, in solution, exist in...
| Main Authors: | , , |
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| 格式: | Journal article |
| 語言: | English |
| 出版: |
1997
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