Flexible and versatile pincer-type PGeP and PSnP ligand frameworks
We describe the synthesis and application of two phosphine-functionalized pincer-type N-heterocyclic carbene analogues [(PNNP)E] (E = Ge, Sn) and their reactivity toward main group and precious metal compounds. These flexible tetrelene ligands feature unusual coordination geometries and strong P–E i...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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American Chemical Society
2018
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| _version_ | 1797100525385154560 |
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| author | Bestgen, S Rees, N Goicoechea, J |
| author_facet | Bestgen, S Rees, N Goicoechea, J |
| author_sort | Bestgen, S |
| collection | OXFORD |
| description | We describe the synthesis and application of two phosphine-functionalized pincer-type N-heterocyclic carbene analogues [(PNNP)E] (E = Ge, Sn) and their reactivity toward main group and precious metal compounds. These flexible tetrelene ligands feature unusual coordination geometries and strong P–E interactions and are expandable to digermylene or distannylene compounds on reaction with ECl2. The compounds were also successfully applied as ligands for the synthesis of Cu, Ag, Au, and Pt complexes. The inherent flexibility of the ligand scaffold enabled different structural arrangements driven by the coordination requirements of the metal centers and intermetallic interactions. |
| first_indexed | 2024-03-07T05:38:47Z |
| format | Journal article |
| id | oxford-uuid:e4dbd79c-5fe4-4c84-a152-3725948d2a81 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:38:47Z |
| publishDate | 2018 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:e4dbd79c-5fe4-4c84-a152-3725948d2a812022-03-27T10:19:32ZFlexible and versatile pincer-type PGeP and PSnP ligand frameworksJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e4dbd79c-5fe4-4c84-a152-3725948d2a81EnglishSymplectic Elements at OxfordAmerican Chemical Society2018Bestgen, SRees, NGoicoechea, JWe describe the synthesis and application of two phosphine-functionalized pincer-type N-heterocyclic carbene analogues [(PNNP)E] (E = Ge, Sn) and their reactivity toward main group and precious metal compounds. These flexible tetrelene ligands feature unusual coordination geometries and strong P–E interactions and are expandable to digermylene or distannylene compounds on reaction with ECl2. The compounds were also successfully applied as ligands for the synthesis of Cu, Ag, Au, and Pt complexes. The inherent flexibility of the ligand scaffold enabled different structural arrangements driven by the coordination requirements of the metal centers and intermetallic interactions. |
| spellingShingle | Bestgen, S Rees, N Goicoechea, J Flexible and versatile pincer-type PGeP and PSnP ligand frameworks |
| title | Flexible and versatile pincer-type PGeP and PSnP ligand frameworks |
| title_full | Flexible and versatile pincer-type PGeP and PSnP ligand frameworks |
| title_fullStr | Flexible and versatile pincer-type PGeP and PSnP ligand frameworks |
| title_full_unstemmed | Flexible and versatile pincer-type PGeP and PSnP ligand frameworks |
| title_short | Flexible and versatile pincer-type PGeP and PSnP ligand frameworks |
| title_sort | flexible and versatile pincer type pgep and psnp ligand frameworks |
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