Intramolecular cyclopropanation of unsaturated terminal epoxides and chlorohydrins.

Lithium 2,2,6,6-tetramethylpiperidide (LTMP)-induced intramolecular cyclopropanation of unsaturated terminal epoxides provides an efficient and completely stereoselective entry to bicyclo[3.1.0]hexan-2-ols and bicyclo[4.1.0]heptan-2-ols. Further elaboration of C-5 and C-6 stannyl-substituted bicyclo...

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Hlavní autoři: Hodgson, D, Chung, Y, Nuzzo, I, Freixas, G, Kulikiewicz, K, Cleator, E, Paris, J
Médium: Journal article
Jazyk:English
Vydáno: 2007