Chirality-dependent boron-mediated growth of nitrogen-doped single-walled carbon nanotubes

A change in the relative abundance of single-walled carbon nanotubes, due to the presence of both nitrogen and boron during synthesis, has been identified through Raman and absorption spectroscopy. Raman spectroscopy shows that for two specific branches boron mediates the growth of smaller-diameter...

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Bibliographic Details
Main Authors: Wiltshire, J, Li, L, Herz, L, Nicholas, R, Glerup, M, Sauvajol, J, Khlobystov, A
Format: Journal article
Language:English
Published: 2005
Description
Summary:A change in the relative abundance of single-walled carbon nanotubes, due to the presence of both nitrogen and boron during synthesis, has been identified through Raman and absorption spectroscopy. Raman spectroscopy shows that for two specific branches boron mediates the growth of smaller-diameter zigzag or near-zigzag nanotubes. We combine our experimental results with an improved Kataura model to identify two of the preferentially grown species as (16,0) and (14,1). © 2005 The American Physical Society.