The conformational analysis of phosphine ligands in organometallic complexes. Part 1. Triphenylphosphine coordinated to an achiral metal centre

The conformational analysis of phosphine ligands in organometallic complexes. Part 1. Triphenylphosphine coordinated to an achiral metal centre

The conformational analyses of PPh3 1 and the representative achiral metal complexes [Al(PPh3)(Me)3] 2, [Fe(PPh3)(CO)4] 7 and [Ir(PPh3)2(CO)3]+ 8 possessing tetrahedral and trigonal-bipyramidal geometries are reported, and comparisons between the calculated and solid-state structures are made. The i...

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Bibliographic Details
Main Authors:	Costello, J, Davies, S
Format:	Journal article
Language:	English
Published:	1998

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