Potassium(I) amidotrihydroborate: structure and hydrogen release.

Potassium(I) amidotrihydroborate (KNH(2)BH(3)) is a newly developed potential hydrogen storage material representing a completely different structural motif within the alkali metal amidotrihydroborate group. Evolution of 6.5 wt % hydrogen starting at temperatures as low as 80 degrees C is observed a...

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Bibliographic Details
Main Authors: Diyabalanage, H, Nakagawa, T, Shrestha, R, Semelsberger, T, Davis, B, Scott, B, Burrell, A, David, W, Ryan, K, Jones, M, Edwards, P
Format: Journal article
Language:English
Published: 2010
Description
Summary:Potassium(I) amidotrihydroborate (KNH(2)BH(3)) is a newly developed potential hydrogen storage material representing a completely different structural motif within the alkali metal amidotrihydroborate group. Evolution of 6.5 wt % hydrogen starting at temperatures as low as 80 degrees C is observed and shows a significant change in the hydrogen release profile, as compared to the corresponding lithium and sodium compounds. Here we describe the synthesis, structure, and hydrogen release characteristics of KNH(2)BH(3).