Extended electron transfer and the Frumkin correction

It is now well established that the rate constant for electron transfer between a metal electrode and a given redox moiety (at distance x from the electrode) decays according to exp[ - betax]; values of beta are of the order of 10(8) cm(-1) and depend primarily upon the nature of the intervening med...

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Main Authors: Gavaghan, D, Feldberg, S
格式: Journal article
出版: 2000