tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate.
The relative configuration of tert-butyl 2-de-oxy-4,5-O-iso-propyl-idene-d-gluconate, C(13)H(24)O(6), an inter-mediate in the synthesis of 2-de-oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O-H⋯O hydrogen-bonded mol-ecules running parallel to th...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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| _version_ | 1797100902353469440 |
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| author | Jenkinson, S Booth, K Best, D Fleet, G Watkin, D |
| author_facet | Jenkinson, S Booth, K Best, D Fleet, G Watkin, D |
| author_sort | Jenkinson, S |
| collection | OXFORD |
| description | The relative configuration of tert-butyl 2-de-oxy-4,5-O-iso-propyl-idene-d-gluconate, C(13)H(24)O(6), an inter-mediate in the synthesis of 2-de-oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O-H⋯O hydrogen-bonded mol-ecules running parallel to the a axis. There are two mol-ecules in the asymmetric unit. The absolute configuration was inferred from the use of d-erythrono-lactone as the starting material. |
| first_indexed | 2024-03-07T05:44:17Z |
| format | Journal article |
| id | oxford-uuid:e6a7e0e2-ca16-44cc-8cae-a1b1bb43cb62 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:44:17Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:e6a7e0e2-ca16-44cc-8cae-a1b1bb43cb622022-03-27T10:32:46Ztert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e6a7e0e2-ca16-44cc-8cae-a1b1bb43cb62EnglishSymplectic Elements at Oxford2008Jenkinson, SBooth, KBest, DFleet, GWatkin, DThe relative configuration of tert-butyl 2-de-oxy-4,5-O-iso-propyl-idene-d-gluconate, C(13)H(24)O(6), an inter-mediate in the synthesis of 2-de-oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O-H⋯O hydrogen-bonded mol-ecules running parallel to the a axis. There are two mol-ecules in the asymmetric unit. The absolute configuration was inferred from the use of d-erythrono-lactone as the starting material. |
| spellingShingle | Jenkinson, S Booth, K Best, D Fleet, G Watkin, D tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate. |
| title | tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate. |
| title_full | tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate. |
| title_fullStr | tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate. |
| title_full_unstemmed | tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate. |
| title_short | tert-Butyl 2-de-oxy-4,5-O-isopropyl-idene-d-gluconate. |
| title_sort | tert butyl 2 de oxy 4 5 o isopropyl idene d gluconate |
| work_keys_str_mv | AT jenkinsons tertbutyl2deoxy45oisopropylidenedgluconate AT boothk tertbutyl2deoxy45oisopropylidenedgluconate AT bestd tertbutyl2deoxy45oisopropylidenedgluconate AT fleetg tertbutyl2deoxy45oisopropylidenedgluconate AT watkind tertbutyl2deoxy45oisopropylidenedgluconate |