A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

<p>The encapsulation of a fluoride ion in a trigonal prismatic Cu<small><sup>II</sup></small><small><sub>6</sub></small>-pyrazolato cage results in a small expansion of the Cu<small><sub>6</sub></small>-host. The structura...

全面介紹

書目詳細資料
Main Authors: Mathivathanan, L, Al-Ameed, K, Lazarou, K, Trávníček, Z, Sanakis, Y, Herchel, R, McGrady, JE, Raptis, RG
格式: Journal article
語言:English
出版: Royal Society of Chemistry 2015
實物特徵
總結:<p>The encapsulation of a fluoride ion in a trigonal prismatic Cu<small><sup>II</sup></small><small><sub>6</sub></small>-pyrazolato cage results in a small expansion of the Cu<small><sub>6</sub></small>-host. The structural, electronic and magnetic features of the Cu<small><sub>6</sub></small>-complex, containing an endohedral fluoride in the rare &mu;<small><sub>6</sub></small>-F coordination mode, are compared with those of the parent complex with a vacant Cu<small><sub>6</sub></small>-cage.</p>