A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand
<p>The encapsulation of a fluoride ion in a trigonal prismatic Cu<small><sup>II</sup></small><small><sub>6</sub></small>-pyrazolato cage results in a small expansion of the Cu<small><sub>6</sub></small>-host. The structura...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2015
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| _version_ | 1797100956065726464 |
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| author | Mathivathanan, L Al-Ameed, K Lazarou, K Trávníček, Z Sanakis, Y Herchel, R McGrady, JE Raptis, RG |
| author_facet | Mathivathanan, L Al-Ameed, K Lazarou, K Trávníček, Z Sanakis, Y Herchel, R McGrady, JE Raptis, RG |
| author_sort | Mathivathanan, L |
| collection | OXFORD |
| description | <p>The encapsulation of a fluoride ion in a trigonal prismatic Cu<small><sup>II</sup></small><small><sub>6</sub></small>-pyrazolato cage results in a small expansion of the Cu<small><sub>6</sub></small>-host. The structural, electronic and magnetic features of the Cu<small><sub>6</sub></small>-complex, containing an endohedral fluoride in the rare μ<small><sub>6</sub></small>-F coordination mode, are compared with those of the parent complex with a vacant Cu<small><sub>6</sub></small>-cage.</p> |
| first_indexed | 2024-03-07T05:45:05Z |
| format | Journal article |
| id | oxford-uuid:e6f533fb-28ea-4491-a33c-dc355a28bef9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:45:05Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:e6f533fb-28ea-4491-a33c-dc355a28bef92022-03-27T10:34:55ZA trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligandJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e6f533fb-28ea-4491-a33c-dc355a28bef9EnglishSymplectic ElementsRoyal Society of Chemistry2015Mathivathanan, LAl-Ameed, KLazarou, KTrávníček, ZSanakis, YHerchel, RMcGrady, JERaptis, RG<p>The encapsulation of a fluoride ion in a trigonal prismatic Cu<small><sup>II</sup></small><small><sub>6</sub></small>-pyrazolato cage results in a small expansion of the Cu<small><sub>6</sub></small>-host. The structural, electronic and magnetic features of the Cu<small><sub>6</sub></small>-complex, containing an endohedral fluoride in the rare μ<small><sub>6</sub></small>-F coordination mode, are compared with those of the parent complex with a vacant Cu<small><sub>6</sub></small>-cage.</p> |
| spellingShingle | Mathivathanan, L Al-Ameed, K Lazarou, K Trávníček, Z Sanakis, Y Herchel, R McGrady, JE Raptis, RG A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand |
| title | A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand |
| title_full | A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand |
| title_fullStr | A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand |
| title_full_unstemmed | A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand |
| title_short | A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand |
| title_sort | trigonal prismatic cu6 pyrazolato complex containing a μ6 f ligand |
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