Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation
Reaction of [Ni(COD)2] with PEt3 and octafluoronaphthalene yielded the complex [Ni(η2-1,2-C10F8)(PEt3) 2] 1, which was converted thermally into the C - F activation product trans-[NiF(2-C10F7)(PEt3)2] 2. The crystal structure of 1 shows asymmetric η2 coordination with significant distortions of the...
Full description
Bibliographic Details
| Main Authors: |
Braun, T,
Cronin, L,
Higgitt, C,
McGrady, J,
Perutz, R,
Reinhold, M |
|---|
| Format: | Journal article
|
|---|
| Language: | English |
|---|
| Published: |
2001
|
|---|