Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation
Reaction of [Ni(COD)2] with PEt3 and octafluoronaphthalene yielded the complex [Ni(η2-1,2-C10F8)(PEt3) 2] 1, which was converted thermally into the C - F activation product trans-[NiF(2-C10F7)(PEt3)2] 2. The crystal structure of 1 shows asymmetric η2 coordination with significant distortions of the...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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2001
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| _version_ | 1797101021871210496 |
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| author | Braun, T Cronin, L Higgitt, C McGrady, J Perutz, R Reinhold, M |
| author_facet | Braun, T Cronin, L Higgitt, C McGrady, J Perutz, R Reinhold, M |
| author_sort | Braun, T |
| collection | OXFORD |
| description | Reaction of [Ni(COD)2] with PEt3 and octafluoronaphthalene yielded the complex [Ni(η2-1,2-C10F8)(PEt3) 2] 1, which was converted thermally into the C - F activation product trans-[NiF(2-C10F7)(PEt3)2] 2. The crystal structure of 1 shows asymmetric η2 coordination with significant distortions of the naphthalene unit compared to the "free" ligand; DFT calculations reproduce the principal features of the geometry. |
| first_indexed | 2024-03-07T05:45:59Z |
| format | Journal article |
| id | oxford-uuid:e73bf48f-1ad0-4500-b712-12c154c5a790 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:45:59Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:e73bf48f-1ad0-4500-b712-12c154c5a7902022-03-27T10:37:01ZCoordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e73bf48f-1ad0-4500-b712-12c154c5a790EnglishSymplectic Elements at Oxford2001Braun, TCronin, LHiggitt, CMcGrady, JPerutz, RReinhold, MReaction of [Ni(COD)2] with PEt3 and octafluoronaphthalene yielded the complex [Ni(η2-1,2-C10F8)(PEt3) 2] 1, which was converted thermally into the C - F activation product trans-[NiF(2-C10F7)(PEt3)2] 2. The crystal structure of 1 shows asymmetric η2 coordination with significant distortions of the naphthalene unit compared to the "free" ligand; DFT calculations reproduce the principal features of the geometry. |
| spellingShingle | Braun, T Cronin, L Higgitt, C McGrady, J Perutz, R Reinhold, M Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation |
| title | Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation |
| title_full | Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation |
| title_fullStr | Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation |
| title_full_unstemmed | Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation |
| title_short | Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation |
| title_sort | coordination and oxidative addition of octafluoronaphthalene at a nickel centre isolation of an intermediate in c f bond activation |
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