Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation

Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation

Reaction of [Ni(COD)2] with PEt3 and octafluoronaphthalene yielded the complex [Ni(η2-1,2-C10F8)(PEt3) 2] 1, which was converted thermally into the C - F activation product trans-[NiF(2-C10F7)(PEt3)2] 2. The crystal structure of 1 shows asymmetric η2 coordination with significant distortions of the...

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Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Braun, T, Cronin, L, Higgitt, C, McGrady, J, Perutz, R, Reinhold, M
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	2001

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