Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis
<p>The synthesis of rhodium complexes with weakly binding highly fluorinated benzene ligands is described: 1,2,3‐F<sub>3</sub>C<sub>6</sub>H<sub>3</sub>, 1,2,3,4‐F<sub>4</sub>C<sub>6</sub>H<sub>2</sub> and 1,2,3,4...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2019
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| _version_ | 1797101127947255808 |
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| author | McKay, A Barwick–Silk, J Savage, M Willis, M Weller, A |
| author_facet | McKay, A Barwick–Silk, J Savage, M Willis, M Weller, A |
| author_sort | McKay, A |
| collection | OXFORD |
| description | <p>The synthesis of rhodium complexes with weakly binding highly fluorinated benzene ligands is described: 1,2,3‐F<sub>3</sub>C<sub>6</sub>H<sub>3</sub>, 1,2,3,4‐F<sub>4</sub>C<sub>6</sub>H<sub>2</sub> and 1,2,3,4,5‐F<sub>5</sub>C<sub>6</sub>H are shown to bind with cationic [Rh(Cy<sub>2</sub>P(CH<sub>2</sub>)<sub><em>x</em></sub>PCy<sub>2</sub>)]<sup>+</sup> fragments (<em>x=</em>1, 2). Their structures and reactivity with alkenes, and use in catalysis for promoting the Tishchenko reaction of a simple aldehyde, are demonstrated. Key to the synthesis of these complexes is the highly concentrated reaction conditions and use of the [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]<sup>−</sup> anion.</p> |
| first_indexed | 2024-03-07T05:47:27Z |
| format | Journal article |
| id | oxford-uuid:e7b1f205-39dc-4034-80fc-e05f9540e491 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:47:27Z |
| publishDate | 2019 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:e7b1f205-39dc-4034-80fc-e05f9540e4912022-03-27T10:40:51ZSynthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysisJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e7b1f205-39dc-4034-80fc-e05f9540e491EnglishSymplectic Elements at OxfordWiley2019McKay, ABarwick–Silk, JSavage, MWillis, MWeller, A<p>The synthesis of rhodium complexes with weakly binding highly fluorinated benzene ligands is described: 1,2,3‐F<sub>3</sub>C<sub>6</sub>H<sub>3</sub>, 1,2,3,4‐F<sub>4</sub>C<sub>6</sub>H<sub>2</sub> and 1,2,3,4,5‐F<sub>5</sub>C<sub>6</sub>H are shown to bind with cationic [Rh(Cy<sub>2</sub>P(CH<sub>2</sub>)<sub><em>x</em></sub>PCy<sub>2</sub>)]<sup>+</sup> fragments (<em>x=</em>1, 2). Their structures and reactivity with alkenes, and use in catalysis for promoting the Tishchenko reaction of a simple aldehyde, are demonstrated. Key to the synthesis of these complexes is the highly concentrated reaction conditions and use of the [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]<sup>−</sup> anion.</p> |
| spellingShingle | McKay, A Barwick–Silk, J Savage, M Willis, M Weller, A Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis |
| title | Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis |
| title_full | Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis |
| title_fullStr | Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis |
| title_full_unstemmed | Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis |
| title_short | Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis |
| title_sort | synthesis of highly fluorinated arene complexes of rh chelating phosphine cations and their use in synthesis and catalysis |
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